Research/Sitter/MAGNDATA / 2.111_TbFe6Ge6.mcif

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Spin lattice of Tb1Fe6Ge6Spin lattice of Tb1Fe6Ge6

Tb1Fe6Ge6

MAGNDATA entry 2.111 · source
noncollinear ferrimagnet
Opposite moments of different size leave a net magnetisation.
ordered ≤ 9.5 K (−264 °C)Colour: where that sits relative to 25 °C. Saturation: how much margin it has.
Structure · 11 properties
Magnetic groupP c′ BNS 7.26
Point groupm′
Parent space groupC m c m No. 63
Spinscoplanar · net moment 28 μB per cell
Propagation[0 0 0] · [1 0 0] 2k
Cella 8.1292 · b 17.7323 · c 5.1189 Å · α 90° · β 90° · γ 90°
Transition9.5 K (−264 °C)
Measured at1.4 K
Magnetic ionsFe, Tb
Largest moment component8.8 μB
MethodNPD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in P c′ →
Atom sites · 32 sites · CSV
siteelementxyzmambmc|m| (μB)
Tb1_1Tb00.1220.258.803.79.5462
Tb1_2Tb0.50.6220.25−1.80−3.74.1146
Tb2_1Tb00.6280.258.80−3.79.5462
Tb2_2Tb0.50.1280.25−1.803.74.1146
Ge1_1Ge00.96240.25
Ge1_2Ge0.50.46240.25
Ge2_1Ge00.45670.25
Ge2_2Ge0.50.95670.25
Ge3_1Ge00.7870.25
Ge3_2Ge0.50.2870.25
Ge4_1Ge00.29550.25
Ge4_2Ge0.50.79550.25
Ge5_1Ge0.34770.12520.25
Ge5_2Ge0.65230.87480.75
Ge5_3Ge0.84770.62520.25
Ge5_4Ge0.15230.37480.75
Ge6_1Ge0.84770.12480.25
Ge6_2Ge0.15230.87520.75
Ge6_3Ge0.34770.62480.25
Ge6_4Ge0.65230.37520.75
Fe1_1Fe0.250.2502.29002.29
Fe1_2Fe0.750.750.5−2.29002.29
Fe1_3Fe0.750.250.5−2.29002.29
Fe1_4Fe0.250.7502.29002.29
Fe2_1Fe0.2508002.29002.29
Fe2_2Fe0.749200.5−2.29002.29
Fe2_3Fe0.75080.50−2.29002.29
Fe2_4Fe0.24920.50.52.29002.29
Fe3_1Fe0.74920.8760.25−2.29002.29
Fe3_2Fe0.25080.1240.752.29002.29
Fe3_3Fe0.24920.3760.252.29002.29
Fe3_4Fe0.75080.6240.75−2.29002.29

Moment components are along the crystal axes a, b, c (μB), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

O. Zaharko et al. J. Magn. Magn. Mater. (1998) · doi:10.1016/S0304-8853(98)00148-6

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 2.111_TbFe6Ge6.mcif from MAGNDATA · entry page

sha256 of this copy: 5723958c904ff81706878fa4a7d1cc368e7d7572ceb0d0d00ce94e669179f3a6
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 2.111_TbFe6Ge6.mcif.