Research/Sitter/MAGNDATA / 1.480_Mn2CoReO6.mcif

Mn₂CoReO₆

MAGNDATA entry 1.480 · source

noncollinear antiferromagnet

All moments add up to a net magnetisation: an ordinary magnet. Spin splitting is the same in every direction (s-wave).

ordered ≤ 94 K (−179 °C)Colour: where that sits relative to 25 °C. Saturation: how much margin it has.

Structure · 10 properties

Magnetic group	P_S 1 BNS 2.7
Parent space group	P 2₁/n No. 14
Spins	coplanar · net moment 0 μ_B per cell
Propagation	[1/2 1/2 0] 1k
Cell	a 10.4608 · b 10.6842 · c 7.6293 Å · α 90° · β 90° · γ 90°
Transition	94 K (−179 °C)
Measured at	60 K
Magnetic ions	Co, Mn, Re
Largest moment component	2.41 μ_B
Method	NPD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in P_S 1 →

Atom sites · 16 sites · CSV

site	element	x	y	z	m_a	m_b	m_c	\|m\| (μ_B)
Mn1_1	Mn	0.2465	0.2757	0.746	−1.323	1.156	1.657	2.415
Mn1_2	Mn	0.0035	0.5256	0.754	−1.323	1.156	1.657	2.415
Co1_1	Co	0.2465	0.2757	0.746
Co1_2	Co	0.0035	0.5256	0.754
Mn2_1	Mn	0.25	0	0.5
Mn2_2	Mn	0	0.25	0
Co2_1	Co	0.25	0	0.5	0	2.41	0	2.41
Co2_2	Co	0	0.25	0	0	−2.41	0	2.41
Re1_1	Re	0.25	0	0	0	−0.804	0	0.804
Re1_2	Re	0	0.25	0.5	0	−0.804	0	0.804
O1_1	O	0.1709	0.1522	0.9296
O1_2	O	0.079	0.4022	0.5704
O2_1	O	0.1553	0.1598	0.5574
O2_2	O	0.0947	0.4098	0.9426
O3_1	O	0.4401	0.2167	0.7378
O3_2	O	0.8098	0.4667	0.7622

Moment components are along the crystal axes a, b, c (μ_B), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

C.E. Frank et al. Chem. Commun. (2019) · doi:10.1039/c9cc00038k

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 1.480_Mn2CoReO6.mcif from MAGNDATA · entry page

sha256 of this copy: dd4d65577e1dc0a7e55549d78365c5c387066a378c714cad566e2d9eff218d16
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 1.480_Mn2CoReO6.mcif.