Research/Sitter/MAGNDATA / 1.1.71_YMnO3.mcif

YMnO₃

MAGNDATA entry 1.1.71 · source

incommensurate spin-density wave

Incommensurate: the magnetic pattern repeats every so many cells, but not a whole number of them, so it never lines up with the crystal lattice. Here it's a spin-density wave: the size of the spin swells and shrinks as you move along.

ordered ≤ 42 K (−231 °C)Colour: where that sits relative to 25 °C. Saturation: how much margin it has.

Structure · 11 properties

Magnetic group	Pnma1′(α00)0sss
Point group	mmm1′
Parent space group	P n m a No. 62
Repeats every	2.3 cells along a (not a whole number: that's what incommensurate means)
Propagation	[0.4344 0 0] 1k
Cell	a 5.797 · b 7.3606 · c 5.2404 Å · α 90° · β 90° · γ 90°
Transition	42 K (−231 °C)
Measured at	1.7 K
Magnetic ions	Mn
Largest moment component	3.89 μ_B
Method	NPD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in Pnma1′(α00)0sss →

Atom sites · 4 sites · CSV

site	element	x	y	z
Y1	Y	0.0855	0.25	0.9819
Mn1	Mn	0	0	0.5
O1	O	0.466	0.25	0.1093
O2	O	0.3266	0.052	0.7005

Incommensurate: the moments are modulated; the picture evaluates each atom's Fourier series at its own phase.

Moment components are along the crystal axes a, b, c (μ_B), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

A Munoz et al. J. Phys.: Condens. Matter (2002) · doi:10.1088/0953-8984/14/12/315

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 1.1.71_YMnO3.mcif from MAGNDATA · entry page

sha256 of this copy: f4d4275b9a800428509193b5f09c017a2271a6f35cf5a5035bfec1ba8cfd9209
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 1.1.71_YMnO3.mcif.