Research/Sitter/MAGNDATA / 1.0.37_CsMnI3.mcif

CsMnI₃

MAGNDATA entry 1.0.37 · source

noncollinear antiferromagnet

All moments add up to a net magnetisation: an ordinary magnet. Spin splitting is the same in every direction (s-wave).

ordered ≤ 11.1 K (−262 °C)Colour: where that sits relative to 25 °C. Saturation: how much margin it has.

Structure · 10 properties

Magnetic group	C m′ c 2₁′ BNS 36.174
Parent space group	P 6₃/m m c No. 194
Spins	coplanar · net moment 0 μ_B per cell
Propagation	[1/3 1/3 0] · [0 0 0] 1k
Cell	a 24.333 · b 24.333 · c 6.871 Å · α 90° · β 90° · γ 120°
Transition	11.1 K (−262 °C)
Measured at	4.2 K
Magnetic ions	Mn
Largest moment component	3.36 μ_B
Method	NSD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in C m′ c 2₁′ →

Atom sites · 9 sites · CSV

site	element	x	y	z	m_a	m_b	m_c	\|m\| (μ_B)
Cs1_1	Cs	0.1111	0.2222	0.75
Cs1_2	Cs	0.2222	0.1111	0.25
Mn1_1	Mn	0	0	0	0	0	3.36	3.36
Mn1_2	Mn	0	0.3333	0	2.54	0	−2.2	3.3603
I1_1	I	0.0555	0.111	0.25
I1_2	I	0.889	0.9445	0.25
I1_3	I	0.0555	0.4443	0.25
I1_4	I	0.889	0.2778	0.25
I1_5	I	0.0555	0.2778	0.25

Moment components are along the crystal axes a, b, c (μ_B), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

H. W. Zandbergen et al. JOURNAL OF SOLID STATE CHEMISTRY (1980) · doi:10.1016/0022-4596(80)90534-4

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 1.0.37_CsMnI3.mcif from MAGNDATA · entry page

sha256 of this copy: a2853a4285328be22ece0e7407119f123b7a1287e3da0b14eec5ccdec41f90c9
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 1.0.37_CsMnI3.mcif.