Research/Sitter/MAGNDATA / 0.966_V2WO6.mcif

V₂W₁O₆

MAGNDATA entry 0.966 · source

antiferromagnet

No net magnetisation, and up and down sublattices are related by a shift or by inversion, so the bands stay spin-degenerate: a conventional antiferromagnet.

Spin group ¹4/¹m¹m¹m × ²1: each symmetry marked ¹ keeps every spin, ² swaps up and down.

ordered ≤ 117 K (−156 °C)Colour: where that sits relative to 25 °C. Saturation: how much margin it has.

Structure · 11 properties

Magnetic group	P n′ n m BNS 58.395
Point group	m′mm
Parent space group	P 4₂/m n m No. 136
Spins	collinear · net moment 0 μ_B per cell
Propagation	[0 0 0] 1k
Cell	a 4.6213 · b 4.6213 · c 8.8864 Å · α 90° · β 90° · γ 90°
Transition	117 K (−156 °C)
Measured at	77 K
Magnetic ions	V
Largest moment component	0.9 μ_B
Method	NPD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in P n′ n m →

Atom sites · 4 sites · CSV

site	element	x	y	z	m_a	m_b	m_c	\|m\| (μ_B)
W1	W	0	0	0
V1	V	0	0	0.3347	0.9	0	0	0.9
O1	O	0.2943	0.2943	0
O2	O	0.3018	0.3018	0.3385

Moment components are along the crystal axes a, b, c (μ_B), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

D. Fruchart et al. J. Physique (1980) · doi:10.1051/jphys:01980004102014100

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 0.966_V2WO6.mcif from MAGNDATA · entry page

sha256 of this copy: 162cc249b96988ba9fb7bdd54fd821c623e1f6ad3dea63c4a560aab53a681a59
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 0.966_V2WO6.mcif.

V2W1O6

Symmetry

Source

Original file

V₂W₁O₆