Research/Sitter/MAGNDATA / 0.599_CaMnSi.mcif

CaMnSi

MAGNDATA entry 0.599 · source

antiferromagnet

No net magnetisation, and up and down sublattices are related by a shift or by inversion, so the bands stay spin-degenerate: a conventional antiferromagnet.

Spin group ¹4/¹m¹m¹m × ²1: each symmetry marked ¹ keeps every spin, ² swaps up and down.

ordered ≤ 360 K (87 °C)Colour: where that sits relative to 25 °C. Saturation: how much margin it has.

Structure · 10 properties

Magnetic group	P 4′/n′ m ′ m BNS 129.416
Parent space group	P 4/n m m No. 129
Spins	collinear · net moment 0 μ_B per cell
Propagation	[0 0 0] 1k
Cell	a 4.172 · b 4.172 · c 7.121 Å · α 90° · β 90° · γ 90°
Transition	360 K (87 °C)
Measured at	2 K
Magnetic ions	Mn
Largest moment component	3.27 μ_B
Method	NPD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in P 4′/n′ m ′ m →

Atom sites · 3 sites · CSV

site	element	x	y	z	m_a	m_b	m_c	\|m\| (μ_B)
Mn1	Mn	0.25	0.75	0	0	0	3.27	3.27
Ca1	Ca	0.25	0.25	0.669
Si1	Si	0.25	0.25	0.213

Moment components are along the crystal axes a, b, c (μ_B), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

R. Welter et al. Solid State Communications (1996) · doi:10.1016/0038-1098(95)00693-1

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 0.599_CaMnSi.mcif from MAGNDATA · entry page

sha256 of this copy: e0ecb3b32d8aeaa6e328c73fd1a2a1b0bbd4bc477521bdf68751a3dc129d8a87
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 0.599_CaMnSi.mcif.