Research/Sitter/MAGNDATA / 0.352_TbFeO3.mcif

TbFeO₃

MAGNDATA entry 0.352 · source

noncoplanar ferrimagnet

Opposite moments of different size leave a net magnetisation.

ordered ≤ 8.4 K (−265 °C)Colour: where that sits relative to 25 °C. Saturation: how much margin it has.

Structure · 10 properties

Magnetic group	P n′ m′ a BNS 62.446
Parent space group	P b n m No. 62
Spins	noncoplanar · net moment 9.6 μ_B per cell
Propagation	[0 0 0] 1k
Cell	a 5.326 · b 5.602 · c 7.635 Å · α 90° · β 90° · γ 90°
Transition	8.4 K (−265 °C)
Measured at	4.2 K
Magnetic ions	Fe, Tb
Largest moment component	4.8 μ_B
Method	NPD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in P n′ m′ a →

Atom sites · 4 sites · CSV

site	element	x	y	z	m_a	m_b	m_c	\|m\| (μ_B)
Fe1	Fe	0	0.5	0	0	0	4.8	4.8
Tb1	Tb	0.9815	0.066	0.25	2.4	1.9	0	3.061
O1	O	0.61	0.042	0.75
O2	O	0.692	0.306	0.053

Moment components are along the crystal axes a, b, c (μ_B), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

E. Bertaut et al. Solid State Communications (1967) · doi:10.1016/0038-1098(67)90276-1

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 0.352_TbFeO3.mcif from MAGNDATA · entry page

sha256 of this copy: 15697ab97b27d79093e5be5f9e0535a92e6741940fcf35b7d37d14d099637cd7
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 0.352_TbFeO3.mcif.