Research/Sitter/MAGNDATA / 0.233_Mn2FeSbO6.mcif

Mn₂FeSbO₆

MAGNDATA entry 0.233 · source

s-wave ferrimagnet

Opposite moments of different size leave a net magnetisation.

Spin group ¹3̄: each symmetry marked ¹ keeps every spin, ² swaps up and down.

ordered ≤ 260 K (−13 °C)Colour: where that sits relative to 25 °C. Saturation: how much margin it has.

Structure · 10 properties

Magnetic group	P 1 BNS 2.4
Parent space group	R3 No. 148
Spins	collinear · net moment 4.2 μ_B per cell
Propagation	[0 0 0] 1k
Cell	a 5.2321 · b 5.2321 · c 14.3722 Å · α 90° · β 90° · γ 120°
Transition	260 K (−13 °C)
Measured at	150 K
Magnetic ions	Fe, Mn
Largest moment component	3.2 μ_B
Method	NPD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in P 1 →

Atom sites · 6 sites · CSV

site	element	x	y	z	m_a	m_b	m_c	\|m\| (μ_B)
Mn1	Mn	0	0	0.1384	−2.5	0	0	2.5
Fe1	Fe	0	0	0.3486	3.2	0	0	3.2
Sb1	Sb	0	0	0.3486
O1_1	O	0.2897	0.9789	0.2562
O1_2	O	0.0211	0.3108	0.2562
O1_3	O	0.6892	0.7103	0.2562

Moment components are along the crystal axes a, b, c (μ_B), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

A.J. Dos santos-Garcia et al. Angew. Chem. Int. Ed. (2017) · doi:10.1002/anie.201609762

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 0.233_Mn2FeSbO6.mcif from MAGNDATA · entry page

sha256 of this copy: bed317ffe5acf88e4c3d6ae7419061c20a653eafb335d72f1e7e02e9b938d94c
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 0.233_Mn2FeSbO6.mcif.