Research/Sitter/MAGNDATA / 0.1052_Fe3S4.mcif

Fe₃S₄

MAGNDATA entry 0.1052 · source

s-wave ferrimagnet

Opposite moments of different size leave a net magnetisation.

Spin group ¹m¹3̄¹m: each symmetry marked ¹ keeps every spin, ² swaps up and down.

Structure · 10 properties

Magnetic group	I 4₁/a m′ d′ BNS 141.557
Point group	4/mm′m′
Parent space group	F d 3 m No. 227
Spins	collinear · net moment 25.44 μ_B per cell
Propagation	[0 0 0] 1k
Cell	a 9.8585 · b 9.8585 · c 9.8585 Å · α 90° · β 90° · γ 90°
Measured at	100 K
Magnetic ions	Fe
Largest moment component	3.2 μ_B
Method	NPD

Symmetry

Stereogram of the magnetic point group: each operation applied to one direction. Filled = upper hemisphere, ring = lower; red operations include time reversal. Lines are mirrors; polygons are 2/3/4/6-fold axes; the centre ring is inversion.

Every structure in I 4₁/a m′ d′ →

Atom sites · 3 sites · CSV

site	element	x	y	z	m_a	m_b	m_c	\|m\| (μ_B)
Fe1	Fe	0	0	0	0	0	3.2	3.2
Fe2	Fe	0.375	0.375	0.375	0	0	−3.19	3.19
S1	S	0.1299	0.1299	0.1299

Moment components are along the crystal axes a, b, c (μ_B), as magCIF writes them. Symmetry generates the rest of the cell from these sites.

Source

L. Chang et al. JOURNAL OF GEOPHYSICAL RESEARCH (2009) · doi:10.1029/2008JB006260

Cite the original paper and MAGNDATA, not this mirror.

Original file

⬇ 0.1052_Fe3S4.mcif from MAGNDATA · entry page

sha256 of this copy: 95728a757f79f153dd1b68ef9dff678d271ab1cc142bd7709e3f41925e4ebe30
The mirror keeps the bytes Bilbao served, so the original should hash the same unless MAGNDATA has revised the entry since: shasum -a 256 0.1052_Fe3S4.mcif.